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Just as their characters’ love affair was not meant to be, neither was their off-screen romance.

Eventually, Candice Accola would become Candace King (after marrying The Fray’s Joe King) and Zach would go on to date another actress whom he met on the set of , Leighton Meester and Sebastian Stan sadly did not find relationship success - on or off-screen.

The couple’s on-screen romance as Brooke and Julian (better known as "Brulian") was one of the show’s highlights.

Audiences watched the pair have to fight for the relationship, overcome hardships and finally triumph.

For years, fans may have cooed over the two together in public, but their time as a couple actually ended just prior to the series finale.

While vampires are supposed to live forever, this relationship certainly did not. Speculation about why the couple split floated around the CW rumor mill for a while but the biggest shock came not long after their breakup.

Here are 16 CW Couples You Had No Idea Were Together In Real Life.

The Australian star and the British actor reportedly began their real-life love affair back in 2014.

While the show might have quashed any hope we had to see the two of them live out their wildest dreams, the good news is, this couple is still together.

After several sightings together, in early 2017, Benoist and Wood confirmed their real-life relationship and have since been pretty outspoken with their PDA.

In fact, their adorable public words of encouragement and obvious affection for each other gives all of us hope that love can save the day Accola and Roerig may not have been the most highly publicized couple to come out of this CW show, but they were utterly adored nonetheless.

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